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Electronic state and photosensitivity of metal alkoxides chemically modified with β-diketones
http://hdl.handle.net/10132/3421
http://hdl.handle.net/10132/34212b58b325-471b-4cee-9718-bf66ffb918c7
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
kowada_2009_05_23.pdf (151.1 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2010-07-23 | |||||
| タイトル | ||||||
| タイトル | Electronic state and photosensitivity of metal alkoxides chemically modified with β-diketones | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Micro patterning | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | First principle molecular orbital calculation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | DV-Xα cluster method | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Photodissociation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Optical absorption | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Kowada, Y
× Kowada, Y× Noma, N |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Electronic state and optical absorption spectra of metal alkoxides stabilized with β-diketones, which had various substituents, were calculated by the first principle molecular orbital methods. The characteristics of the optical absorption and the mechanism of the photodissociation of alkoxides with irradiation of light were discussed. The position of the first peak observed near UV region in the theoretical optical absorption spectra corresponded to that in the experimental ones with about 25 nm shift toward the shorter wavelength. The first absorption peak observed in the visible range was originated from the electron transitions to molecular orbitals including the antibonding components of the C-O bonding in the chelate ring. The results suggested that the bonding nature of chelate rings should be important to understand the photosensitivity of the chemically modified titanium alkoxides. | |||||
| 書誌情報 |
Journal of Sol-Gel Science and Technology 巻 52, 号 1, p. 166-169, 発行日 2009-05-23 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 15734846 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1007/s10971-009-1994-2 | |||||
| 権利 | ||||||
| 権利情報 | Copyright Springer Science+Business Media, LLC 2009 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | Springer Netherlands | |||||
| 関係URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.springerlink.com/content/100301/ | |||||
| 関連名称 | http://www.springerlink.com/content/100301/ | |||||
